Hi Mark
I assume when you say polycarbonate you mean solid sheet not multiwall as used on conservatory roofs!
There are many differences between polycarbonate and acrylic and much depends on how much of a radius you need on your window, what thickness of glazing material you envisage, size of unsupported plastic, how deep a rebate to fix, method of fixing, security issues and possible abrasion problems. Add budget to that as poly is more expensive like for like.
Thickness will determine radius possible and vise versa. Unless a tight radius you don't need to heat either but both possible as they are thermoformable plastics.
Acrylic is more rigid than poly but also more brittle. The flexibility of poly is one of it's strengths and preferable for security but because of that it scratches more easily, (there are variants with a coated surface to improve that), however because of the flexibility it needs a deeper rebate and ideally some mechanical fixing, it can also be attacked by solvents so care is needed. Note that both materials have one surface coated to protect against UV degradation so have to fixed that side out.
Plenty of information out there especially from ICI / Perspex or if you go on to the Amari Plastics site they have quite a bit from memory though will be Makalon rather than Perspex it doesn't matter. They have a branch on TVTE next to the retail shopping centre which is probably your nearest outlet, not too far away and the right side of those bl**dy roadworks for you. Also Bay Plastics just North of the Tyne Tunnel carries a lot of stock and have knowledgeable staff.
If you post some details of your project I might be able to offer advice as will others on the forum.
cheers
Bob
http://www.amariplastics.com/
http://www.bayplastics.co.uk/